(4,7-Diphenyl-1,10-phenanthroline-κ2 N,N′)dimethylbis(thiocyanato-κN)tin(IV)
نویسندگان
چکیده
In the title compound, [Sn(CH(3))(2)(NSC)(2)(C(24)H(16)N(2))], a 1:1 adduct of dimethyl-tin diisothio-cyanate with 4,7-diphenyl-1,10-phenanthroline, the Sn(IV) atom shows a slightly distorted octa-hedral SnC(2)N(4) coordination. The methyl groups are trans to each other in the octa-hedron surrounding the metal atom [C-Sn-C = 176.61 (12)°].
منابع مشابه
Di-n-butylbis(thiocyanato-κN)(1,10-phenanthroline-κ2 N,N′)tin(IV)
In the asymmetric unit of the title compound, [Sn(C(4)H(9))(2)(NCS)(2)(C(12)H(8)N(2))], there are two independent mol-ecules, both lying on a twofold rotation axis. The axis passes through the mid-point of the 1,10 and 5,6 bonds of the N-heterocycle and through the Sn atom. The Sn atoms show a slightly distorted SnC(2)N(4) octa-hedral coordination.
متن کامل(2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline-κ2 N,N′)bis(thiocyanato-κS)mercury(II)
In the mol-ecule of the title compound, [Hg(NCS)(2)(C(26)H(20)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from a chelating 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligand and by two S atoms from two thio-cyanate anions. The ligand ring system is not planar. The dihedral angle between the phenyl rings is 53.20 (3)° . In the crystal st...
متن کاملDimethyl(1,10-phenanthroline-κ2 N,N′)bis(thiocyanato-κN)tin(IV)
The Sn(IV) atom in the title compound, [Sn(CH3)2(NCS)2(C12H8N2)], is located on a twofold rotation axis in a distorted octa-hedral enviroment. The methyl groups are trans to each other [C-Sn-C = 175.7 (3)°], whereas the thio-cyanate groups are cis to each other.
متن کاملcatena-Poly[[dimethylbis(thiocyanato-κN)tin(IV)]-μ-(4,4′-bipyridine-κ2 N:N′)]
The title dimethyl-tin diisothio-cyanate adduct of 4,4'-bipyridine, [Sn(CH(3))(2)(NCS)(2)(C(10)H(8)N(2))](n), adopts a chain motif in which the N-heterocycle functions as a bridge to adjacent all-trans octa-hedrally coordinated tin atoms. The Sn(IV) atom lies on a special position of 2/m site symmetry, the methyl C atom on a special position of 2 site symmetry, and the thio-cyanate and 4,4'-bip...
متن کامل(4,7-Diphenyl-1,10-phenanthroline-κ2 N,N′)diiodidomercury(II)
In the mol-ecule of the title compound, [HgI(2)(C(24)H(16)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the bidentate 4,7-diphenyl-1,10-phenanthroline and two iodide ligands. There is a π-π contact between the pyridine and phenyl rings [centroid-to-centroid distance = 4.2387 (4) Å].
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